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Thursday, April 9, 2026

The Principle of Online Analysers

 



Names and Types of Instruments Working Under the Principle of Online Analysers

Online analysers operate on the principle of continuous or periodic sample extraction from a

process stream, followed by conditioning and analysis in an external unit. This allows the use of more advanced and precise analytical techniques compared to inline systems.

Below is a comprehensive and structured list of instruments that work under the principle of online analysers, categorized by their analytical techniques and applications. This is highly useful for students, industries, laboratories, and researchers.


1. Gas Online Analysers

These instruments continuously extract gas samples and analyze their composition.

Instruments:

  • Online Oxygen (O₂) Analyser

  • Online Carbon Dioxide (CO₂) Analyser

  • Online Carbon Monoxide (CO) Analyser

  • Online Nitrogen Oxides (NOx) Analyser

  • Online Sulfur Dioxide (SO₂) Analyser

  • Online Hydrogen (H₂) Analyser

  • Online Multi-Component Gas Analyser

Principle:

  • Non-Dispersive Infrared (NDIR)

  • Paramagnetic measurement

  • Electrochemical sensing

Applications:

  • Power plants

  • Oil & gas refineries

  • Environmental emission monitoring


2. Liquid Online Analysers

These analysers are used for monitoring liquid samples after extraction and conditioning.

Instruments:

  • Online pH Analyser

  • Online Conductivity Analyser

  • Online Dissolved Oxygen (DO) Analyser

  • Online Turbidity Analyser

  • Online Total Organic Carbon (TOC) Analyser

  • Online Chemical Oxygen Demand (COD) Analyser

  • Online Biological Oxygen Demand (BOD) Analyser

Principle:

Electrochemical, optical, or chemical reaction-based measurements.

Applications:

  • Water and wastewater treatment

  • Food and beverage industry

  • Pharmaceutical manufacturing


3. Spectroscopic Online Analysers

These instruments use light-based techniques for precise chemical analysis.

Instruments:

  • Online UV-Visible Spectrophotometer

  • Online Infrared (IR) Analyser

  • Online Near-Infrared (NIR) Analyser

  • Online Raman Spectrometer

  • Online Fluorescence Analyser

Principle:

Absorption, emission, or scattering of electromagnetic radiation.

Applications:

  • Chemical industries

  • Pharmaceutical quality control

  • Petrochemical plants


4. Chromatographic Online Analysers

Highly sophisticated instruments used for component separation and analysis.

Instruments:

  • Online Gas Chromatograph (GC)

  • Online Liquid Chromatograph (HPLC)

  • Online Process Chromatography System

Principle:

Separation of components based on interaction with stationary and mobile phases.

Applications:

  • Oil & gas industry

  • Petrochemical processing

  • Environmental laboratories


5. Electrochemical Online Analysers

These instruments rely on electrical signals generated by chemical reactions.

Instruments:

  • Online Ion-Selective Electrode (ISE) Analyser

  • Online ORP (Oxidation-Reduction Potential) Analyser

  • Online Electrochemical Gas Sensor

Principle:

Electrochemical potential or current measurement.

Applications:

  • Water treatment plants

  • Chemical industries

  • Environmental monitoring


6. Mass Spectrometry-Based Online Analysers

Used for highly precise and detailed chemical analysis.

Instruments:

  • Online Mass Spectrometer (MS)

  • Online Process Mass Spectrometry System

Principle:

Measurement of mass-to-charge ratio of ions.

Applications:

  • Advanced research laboratories

  • Petrochemical industries

  • Pharmaceutical R&D


7. Thermal and Combustion Online Analysers

Used in energy and combustion-related processes.

Instruments:

  • Online Thermal Conductivity Analyser

  • Online Calorific Value Analyser

  • Online Flue Gas Analyser

Principle:

Heat transfer, combustion efficiency, and gas composition measurement.

Applications:

  • Power plants

  • Boilers and furnaces

  • Energy industries


8. Moisture and Humidity Online Analysers

These instruments measure water content in extracted samples.

Instruments:

  • Online Moisture Analyser (Karl Fischer-based)

  • Online Humidity Analyser

  • Online Dew Point Analyser

Principle:

  • Chemical titration (Karl Fischer)

  • Capacitance or chilled mirror techniques

Applications:

  • Natural gas processing

  • Pharmaceutical production

  • Food industry


9. Wet Chemical Online Analysers

These analysers perform automated chemical reactions for analysis.

Instruments:

  • Online Ammonia Analyser

  • Online Phosphate Analyser

  • Online Silica Analyser

  • Online Chlorine Analyser

  • Online Nitrate/Nitrite Analyser

Principle:

Colorimetric or titration-based chemical reactions.

Applications:

  • Water and wastewater treatment

  • Power plants

  • Environmental monitoring


10. Biological and Biochemical Online Analysers

Used in biotechnology and life sciences.

Instruments:

  • Online Bioreactor Analyser

  • Online Glucose Analyser

  • Online Lactate Analyser

  • Online Enzyme-Based Analyser

  • Online Microbial Monitoring System

Principle:

Enzymatic reactions, biosensors, or optical density measurement.

Applications:

  • Biotechnology industries

  • Pharmaceutical production

  • Fermentation processes


Summary Table

CategoryExample InstrumentsPrincipleKey Applications
GasO₂, CO₂, NOx analysersNDIR, paramagneticOil & Gas, Power
LiquidpH, TOC, CODElectrochemicalWater treatment
SpectroscopicUV, IR, RamanLight interactionPharma, Chemicals
ChromatographicGC, HPLCComponent separationPetrochemical
ElectrochemicalISE, ORPElectrical signalsEnvironment
Mass SpectrometryMS systemsMass analysisResearch
ThermalCalorific analysersHeat transferPower plants
MoistureKF, Dew pointChemical/physicalGas processing
Wet ChemicalAmmonia, SilicaChemical reactionWater plants
BiologicalGlucose, LactateEnzymaticBiotech

Conclusion

Online analysers include a diverse range of instruments that operate on the principle of sample extraction followed by continuous or periodic analysis. These instruments enable:

  • High-precision monitoring

  • Advanced analytical techniques

  • Improved process control

  • Regulatory compliance

For students and researchers, mastering these instruments provides deep insight into modern analytical science. For industries, they are essential tools for ensuring quality, efficiency, and safety in complex processes.




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